Dogs usually pee in the same spot because they can smell their pee (even when you cant see it anymore) and so they'll just reinforce it.
A good homemade recipe to get rid of it is white vinegar and water.
But you can also get good enzymatic sprays which will break down the odour particles instead of masking the smell like:
Nature’s Miracle, Simple Solution, Capture Pet Stain and Odor Neutralizer or Complete Pet Stain and Odor Remover by 8in1.
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